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Reactions with Singlet Oxygen. Singlet oxygen generated by photosensitization of ground-state triplet oxygen,357 prepared by chemical methods,357,358 or resulting from electrical discharge 359 reacts with unsaturated hydrocarbons to give oxygenated products. Depending on the structure of the reacting molecules, allylic hydroperoxides, 1,2-dioxetanes, and endoperoxides may be formed. Oxygenations with singlet oxygen are attractive synthetic reactions and have been studied extensively 60-374 The main reason for this is that the products formed may be readily transformed to functionalized organic compounds 64,366,374-377 Monoalkenes possessing allylic hydrogen are transformed to give allylic hydroperoxides36o-367 [Eq. (9.83)378]. The latter may undergo secondary transformations to give epoxides and divinyl ethers 67 The reaction discovered by Schenck379 is analogous to the ene reaction and involves oxygen attack at one of the olefinic carbons, abstraction of an allylic hydrogen, and the shift of the double bond. The double-bond shift clearly distinguishes the ene reaction from the radical autoxidation of alkenes. Radical autoxidation can yield hydroperoxides, too, but it usually gives a complex reaction mixture. In contrast, oxidation with singlet oxygen introduces oxygen in a highly selective manner into organic compounds. The reactivity of alkenes towards singlet oxygen strongly depends on the electron density of the TC bond, with increasing alkyl substitution bringing about increasing reactivi ty 380 [Eq. (9.84)381]:

Purpose: Returns 1 if expression is syntactically correct; 0, otherwise. Syntax: IsValidExpression (expression) Example: If textField contains 12 +, the following would return 0 (false) because the second addend is absent.

* On the Mac, enter the shortcut for the accent and then type the letter to be accented. For example, to get , type Option+E and then the letter e. In Windows, if the keyboard layout is set to United States-International via the Keyboard icon in the Windows Control Panel you can enter the accent signifier and then type the letter (for example, type ` and then the letter e to get ). To avoid an accent (for example, if you want to begin a quote such as A man rather than have man type a space after the accent character for example, type " and then a space, and then A, rather than typing " and then A.

22. Fox, G. Experience with Distance Education 1998 2002, http://grids.ucs.indiana.edu/ ptliupages/publications/disted/. 23. Biology Workbench at SDSC (San Diego Supercomputer Center), http://workbench.sdsc.edu/. 24. NSF PACI (Partnership in Advanced Computing Infrastructure), EOT (Education and Outreach) Program, http://www.eot.org. 25. Bernholdt, D. E., Fox, G. C., McCracken, N. J., Markowski, R. and Podgorny, M. (2000) Re ections on Three Years of Network-Based Distance Education, Unpublished Report for US Army Corp of Engineers ERDC Vicksburg Miss, July 2000, http://grids.ucs.indiana.edu/ ptliupages/publications/disted/erdctraining00.pdf. 26. NEOS Optimization Server from Argonne National Laboratory, http://www-neos.mcs.anl.gov/ neos/. 27. The Dublin Core Bibliographic Meta Data, http://dublincore.org/. 28. Blackboard Learning System, http://www.blackboard.com/. 29. WebCT Learning System, http://www.webct.com/. 30. Access Grid Conferencing Environment from Argonne National Laboratory, http://www. accessgrid.org. 31. Polycom Conferencing Environment, http://www.polycom.com. 32. Groove Desktop Collaboration Software, http://www.groove.net/. 33. JXTA Peer to Peer environment from Sun Microsystems http://www.jxta.org. 34. Centra Collaboration Environment, http://www.centra.com. 35. Placeware Collaboration Environment, http://www.placeware.com. 36. WebEx Collaboration Environment, http://www.webex.com. 37. Anabas Collaboration Environment, http://www.anabas.com. 38. Interwise Enterprise Communications Platform, http://www.interwise.com. 39. Virtual Network Computing System (VNC), http://www.uk.research.att.com/vnc. 40. Jetspeed Enterprise Portal from Apache, http://jakarta.apache.org/jetspeed/. 41. Jabber Instant Messenger, http://www.jabber.org/.

If GIF is perfect for flat color images, the JPEG format (pronounced jay-peg) is the perfect format for photos and continuous tone graphics. JPEG was originally created to allow photographers to easily transmit photos electronically. Utilizing a lossy compression algorithm, JPEG can achieve some astonishing file size savings by allowing you to compress a 10MB file to about 1MB in most cases. Illustrator lets you set different levels of JPEG compression either by choosing options from a popup menu (Low, Medium, High, Very High, or Maximum) or by moving the Quality slider between 0 and 100. In the Save for Web & Devices dialog box, these settings refer to quality, not compression, so a setting of Maximum means maximum quality (and less compression), not maximum compression and lower quality. Because JPEG compression can result in files that have visible artifacts or look chunky (what you end up seeing are blocks of color rather than detail), you also have the option to apply a blur to minimize such artifacts. You can specify a blur setting of up to 2 pixels using the Blur slider (located under the Quality slider). You can also set JPEG images to progressive, which means that they load incrementally in a browser (similar to GIF s interlacing). You can also specify a matte color for JPEG images (just as with GIFs).